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Equilibrium constants for aqueous Pd(II)-chloride complexes have been extracted from Tagirov et al. (2013) and you may Pt out of Tagirov et al. (2019). The data to possess solid Pd phases, hydroxide-, and you may oxide-buildings had been determined inside the SUPCRT92 (Johnson et al., 1992) with the slop07 database that have 100 percent free opportunity analysis from Sassani and you can Wonder (1998). Investigation for aqueous Ni species were accumulated of Ultraviolet-Apparent spectroscopic tests for the Ni(II)-chloride complexation (Liu et al., 2012). Copper-chloride, Co-chloride complexes, and you can solid Cu mineral levels was taken from the new SUPCRT database. A number of the experimentally computed equilibrium constants utilized were extrapolated to large temperatures by the regression of the constants up against mutual heat. The new altered and you may extrapolated harmony constants and you can reactions utilized in the brand new thermodynamic modelling are listed in Dining table step 1.
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Legitimate experimental investigation for the solubility away from PdS2 unfortuitously don’t occur (Pan and you can Wood, 1994), therefore we tentatively let the stage PdS in order to represent a good Pd component in the pyrite. The new monzonite, because the currently mapped during the breadth, means just 0.01 km3 from magma. Bulk balance computations having fun with Pd tonnages (23–40 t) demonstrate that −1 km3 from magma must create the complete level of Pd on the deposit for a great magma that has ten ppb Pd. Chances are the fresh PGE-results drinks had been raised of depth, possibly acquired from hidden Iron Hide magmas, exploiting pre-mineralization deposit-level structures and you will have been limited to your southern prevent because of the dangling wall blame and you can picrite. After liquids acted in order to remobilize and you may precipitate Pd within the brief, high-degree pockets not related so you can first Cu and you can Au mineralization (Category dos examples).
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